Functionalized separator for next-generation batteries
Advancements in battery technology have dramatically increased demand for improvements in liquid solid separation design, as the separator plays a critical role in ensuring the safety and electrochemical performance of the cells. Current separators, either in commercial usage or under investigation, have yet to meet the high stability and lifespan performance standards necessary to prevent deterioration in the efficiency and reliability of the battery technologies. Recently, considerable effort has been devoted to developing functionalized separators, ranging from designing a variety of new materials and modification methods, and increasingly, to optimizing advanced preparation processes. In order to understand how the mechanisms of vibrating separator performance are affected by different properties, we will first summarize recent research progress and then have in-depth discussions regarding the separator’s significant contribution to enhancing the safety and performance of the cell. We then provide our design strategy for future separators, which not only meets the requirements of different type of batteries, but also aims for multifunctionality. We hope such a perspective could provide new inspiration in the development of liquid solid separator research for future battery technologies.
Filter paper usually removes particles based on five physical effects: gravity, collision, screening, diffusion, and static electricity.6 The removal efficiency of filter paper is closely related to the relative size of the particle diameter and the paper pore size. Smaller pore sizes of the paper correspond to smaller sizes of the particles that it can intercept under the same filtration efficiency.7,8 Adjusting the structure of the filter paper to improve the air flow resistance can increase the residence time of the pollutant particles in the filter paper, resulting in a higher removal efficiency.9,10 However, the filter filtration resistance directly affects the energy consumption of the pressure leaf filter, such that extremely high filtration resistances are not recommended.11 The filtration efficiency has exhibited dependence on the fiber coarseness. Specifically, finer fibers have exhibited higher filtration efficiencies at a constant pressure drop.12 However, air filter paper must maintain a certain porosity to allow air flow. Nanofibers can increase the specific surface area of the filter paper to generate filter papers with small pore sizes, high filtration efficiencies, and high porosities.